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Dragon's Breath was an item added in 1.9 in snapshot 15w33a. It can be collected by right-clicking on the particles either left by the Ender Dragon's Fireball attack while holding a Glass Bottle, right-clicking (again, with a Glass Bottle) the particles the Dragon spits while hovering above the Dragon Nest, or getting it in the creative inventory. It's current sole use is to brew Lingering Potions. It looks like a glass bottle filled with a strange purple gas.